Solutions

TS 10th Class Physical Science 12th Lesson Carbon and its Compounds

Improve Your Learning
I. Reflections on concepts

Question 1.
What are the general molecular formulae of alkanes, alkenes and alkynes?

Answer:
Alkanes - CnH2n+2
Alkenes - CnH2n
Alkynes - CnH2n-2

Question 2.
Name the product other than water formed on burning of ethanal in air.

Answer:
C2H5OH + 3O2 → CO2 + 3H2O + Energy
Carbon dioxide is another product.

Question 3.
Name the simplest ketone and write Its molecular formula.

Answer:
The simplest ketone is Acetone (Propanone) Its molecular formula is CH3COCH3 (or) C3H6O

Question 4.
Name the compound formed by heating ethanol at 443k wIth excess of conc. H2SO4.

Answer:
Ethanol reacts with conc. H2SO4 at about 443K to give ethene, The reaction is as follows

It Is a dehydration reaction. H2SO4 in a dehydrating agent and removes H2O.

Question 5.
Name the product obtained when ethanol is oxidized by either chronic anhydride or alkaline potassium permanganate.

Answer:
Ethyl alcohol (Ethanol) undergoes oxidation to form the product acetaldehyde and finally acetic acid. The reaction Is as follows :


Question 6.
What are homologous series of carbon compounds? Mention any two characteristics of homologous series.

Answer:
Compounds having same functional group are called homologous series. Eq: Alkanes, Alkenes, Alkynes, Halo Alkanes.
Characteristics of homologous series
They have general formula
Eq: General formula of alkanes CnH2n+2
General formula of alkynes: CnH2n-2 etc.
Successive compounds in the series possess a difference of (-CH2) unit.
They possess similar chemical properties due to same functional group.
They show a regular gradation In their physical properties.

Question 7.
Why does carbon form compounds mainly by covalent bonding’?

Answer:
Carbon belongs to 14th group or IV A group in the modem periodic table.
The electronic configuration of carbon is 1s22S22p2. ‘To get octet configuration in its outer shell It has to gain four more electrons to form C4-. Its nucleus has only 6 protons. Therefore it would be difficult for a nucleus with 6 protons to hold 10 electrons. Hence, carbon cannot form C4- ions so easily.
If carbon loses 4 electrons from the outer shell, it has to form C4+’ ions. This require huge amount of energy which is not available normally, Therefore C4+ formation also is remote possibility.
Carbon has to satisfy its tetravalency by sharing electrons with other atoms. It has to form ‘4 covalent bonds either with Its own atoms or atoms of other elements.

Question 8.
Explain how sodium ethoxide is obtained from ethanol. Give chemical equations.

Answer:
Ethanol reacts with sodium to liberate hydrogen and forms sodium ethoxide. The chemical equation is


Question 9.
Explain the cleansing action of soap.

Answer:
1. Soaps and detergents make oil and dirt present on the cloth come out into water, thereby making the cloth clean.
2. Soap has one polar end (the end with - C - o carboxy) and one non-polar end (the end with the hydrocarbon chain) as shown here,
3. The polar end Is hydrophilic in nature and this end is attracted towards water.
4. The non-polar end is hydrophobic, in nature and it is attracted towards grease or oil on the cloth, but not attracted towards water.
5. When soap is dissolved in water, its hydrophobic ends attach themselves to dirt and remove It from cloth, as shown sequentially in the figure.
6. The hydrophobic end of the soap molecules move towards the dirt or grease particle.
7. The hydrophobic ends attached to the dirt particle and try to pull it out.
8. The molecule of soap surround the dirt particles at the centre of the cluster and form a spherical structure called micelle.
9. These micelles remain suspended in water-like particles in a colloidal solution.

10. The various miscelles present in water do not come together to form a precipitate as each micelle repels the other because of the ion-ion repulsion.
11. Thus, the dirt particles remain; trapped in micelles and are easily rinsed away with water. Hence, soap micelles remove dirt by dissolving in water.

Question 10.
Distinguish between esterification and saponification reactions of organic compounds.

Answer:

Esterification Saponification
1) The formation of ester is known as esterification reaction. 1) The formation of soap is known as saponification reaction.
2) Alcohol reacts with carboxylic acids to produce esters. 2) Higher fatty acids reacts with bases to form soaps.
3) Water is the by-product in esterification reaction.
Eg: Ethyl Acetate (CH3COOC2H5)
3) Glycerol is the by-product in saponification reaction
Eg: Sodium stearate. (C17H35COONa)
Question 11.
What happens when a small piece of sodium Is dropped Into ethanol?

Answer:
When a small piece of sodium is dropped into ethanol, it shows brisk effervescence and liberates hydrogen gas and forms sodium ethoxide.


Question 12.
Draw the electronic dot structure of ethane molecule (C2H6)

Answer:

Question 13.
Name the simplest hydrocarbon?

Answer:
Methane (CH4) is the simplest hydrocarbon.

Question 14.
Name the carboxylic acid used as a preservative.

Answer:
Acetic acid - CH3COOH (IUPAC Name Ethanoic Acid)

Question 15.
A mixture of oxygen and ethyne Is burnt for welding; can you tell why a mixture of ethyne and air Is not used?

Answer:
Air consists many gases like N2, CO2, etc., ¡n addition to oxygen.
Production of flame for welding is a combustion reaction, which is generally oxidation reaction.
If air is used it leaves a soot flame. Hence, air is not mixed with ethyne. Only oxygen is mixed with ethyne and used for welding.

Question 16.
What do we call the self linkIng property of carbon?

Answer:
The self-linking property of carbon is called catenation. If any element forms bonds. between its own atoms to give big molecules, we call that property as catenation property.

Question 17.
Give an example for esterification reaction.

Answer:
The reaction between carboxylic acid and an alcohol in the presence of Conc.H2SO4 to form a fruity-odoured substance, ester with the functional

Eg Preparation of ethyl acetate from ethanoic acid and ethanol will be as follows:


Question 18.
Write the chemical equation representing the reaction of preparation of ethanol from ethane.

Answer:
Ethane in the absence of air on heating forms ethanol C2H6→C2H4+H2
Ethanol is prepared on large scale from ethene by addition of water vapour to it in the presence of catalysts like P2O5, Tungsten oxide at high pressure a temperature.


Question 19.
Give the names of functional groups (i) -CHO (ii) -C=O.

Answer:
(i) -CHO aldehyde functional group.
(ii) -C=O Ketone functional group.

Question 20.
Explain the structure of graphite In term of bonding and give one property based on this structure.

Answer:
1. Graphite forms a two-dimensional layer structure with C - C bonds within the layers. There are relatively weak interactions between the layers.
2. In a layer structure, the carbon atoms are in a trigonal planar environment. This is consistent with each carbon atom in sp2 hybridization.
3. Interactions between sp2 orbitals leads to the formation of C - C bonds.
4. Each carbon atom is with one unhybridised ‘p’ orbital.

The arrangement of carbon atoms In graphite layers.
5. The unhybridised ‘p’ orbitals interact to form a ‘?’ system that is delocalised over the whole layer.
6. The interactions (or) London dispersion forces between the layers which are separated by a distance of 3.35 Å are weakened by the presence of water. molecules so that It is easy to cleave graphite.
7. For this reason graphite is used as lubricant and as the ‘lead’ in pencils.

Question 21.
Name the acid present in vinegar.

Answer:
The acid present in vinegar is Ethanoic acid or acetic acid (CH3COOH).
5-8% solution of acetic acid in water Is called vinegar.

Question 22.
How do you appreciate the role of esters In everyday lite?

Answer:
Role of esters in everyday life:
Many esters have pleasant odours, so they are used In perfumes, air refreshers and flavourings, among other things.
Esters are used to give artificial flavouring for sweets, ice creams and soft drinks. In industries, esters are being used as solvents In the manufacture of, cellulose; varnishes and paints, as solvents in pharmaceutical industries and as softeners or plasticizers in plastic and moulding Industries.

Application Of Concepts

Question 1.
Explain with the help of a chemical equation, how an addition reaction is used In vegetable ghee industry.

Answer:
The reaction in which a reagent adds completely on a substance without the removal of small molecules are called addition reaction. Addition of hydrogen in the presence of nickel catalyst to vegetable oil gives ghee. Vegetable oil is unsaturated compound where as ghee is a saturated compound.

Question 2.
a. What are the various possible structural formulae of a compound having molecular formula C3H6O?
b. Give the IUPAC names of the above possible compounds and write their structures.
c. What is the similarity in these compounds?

Answer:
(a) C3H6O
CH3CH2CHO - Ethanal
CH3COCH3 - Propanone

(c) (i) Both ethanol and propanone contain one carbonyl functional group

(ii) Both compounds have same molecular formula,
(iii) Both compounds have the 2sp3 hybridised carbons and one ‘sp2’ hybridised carbon atom.

Question 3.
Allotropy is a property shown by which class of substances: elements, compounds or mixtures? Explain allotropy with suitable examples.

Answer:
Allotropy can be shown by elements.
Allotropy: The property of an element to exist in two or more physical forms having more or less chemical properties but different physical properties is called ‘allotropy’.
Carbon has many allotropes. They are classified into two types.
1) Amorphous forms
2) Crystalline forms
Amorphous forms: Different amorphous forms of carbon are coal, coke, wood charcoal, animal charcoal, lamp black, etc.
Crystallise forms: Different crystalline forms of carbon are diamond, graphite, buckminsterfullerene, nanotubes etc.

Question 4.
Two carbon compounds A and B have molecular formulae C3H8 and C3H6 respectively. Which one of the two is most likely to undergo addition reactions? Justify your answer.

Answer:

It is a saturated hydrocarbon. It shows substitution reaction.

This is an unsaturated hydrocarbon. Hence it shows addition to become saturated. During the reactions, addition of reagent takes place at the double-bonded carbon atoms.


Question 5.
1 ml of glacial acetic acid and 1 ml of ethanol are mixed together in a test tube. Few drops of concentrated sulphuric acid is added to the mixture and warmed ¡n a water bath for 5 min. Answer the following:
(a) Name the resultant compound formed.
(b) Represent the above change by a chemical equation?
(c) What name is given to such a reaction?
(d) What are the special characteristics of the compound formed?

Answer:
(a) Ethyl acetate (CH3COOC2H5) an ester.

(c) Esterification reaction
(d) The formed compound when poured into water, we observe a sweet fruit odour.

Question 6.
Give the IUPAC name of the following compounds. If more than one compound is possible name at least two of them.
(i) An aldehyde derived from ethane.
(ii) A ketone derived from butane.
(iii) A chloride derived from propane.
(iv) An alcohol derived from pentane.

Answer:
(i) An aldehyde derived from ethane is "Ethanal" (CH3CHO) (or)
(ii) Ketone derived from butane s Butanone (Or) Butane-2- one.

(iii) Chloride derived from propane is
(a) Propyl chloride
CH3 - CH2 - CH2Cl
(b) 2 - Chloro - Propane

(iv) Alcohol derived from pentane


Question 7.
Write the IUPAC name of the next homologous of CH2OHCH2CH3.

Answer:

Question 8.
How do you condemn the use of alcohol as a social practice?

Answer:
Consumption of alcohol ¡n the form of beverages is harmful to health.
It causes severe damage to blood circulation system.
Addiction to alcohol drinking leads to heart diseases and damages the liver.
It also causes ulcers in small intestines due to increased acidity and damages the digestive system.
Alcohol which is consumed in raw form under the names liquor, gudumba is more harmful to health due to adulteration.
Alcohol mixed with pyridine is called denatured spirit. Consumption of denatured spirit causes blindness and death.
Hence use of alcohol is a social evil which harms the society.

Question 9.
An organic compound with molecular formula C2H4O2 produces brisk effervescence on addition of sodium carbonate/bicarbonate.
Answer the following:
(a) Identify the organic compound.
(b) Write the chemical equation for the above reaction.
(C) Name the gas evolved.
(d) How will you test the gas evolved?
(e) List two important uses of the above compound.

Answer:
a) CH3COOH (EtharioiC acid)
b) 2CH3COOH + Na2CO3 → 2CH3COONa + H2 + CO2
CH3COOH + NaHCO3 → CH3COONa + CO2 + H2O
C) Carbon dioxide (CO2)
d) When the evolved gas is passed into lime water, lime water turns milky white. Basing on the observation we conclude that the evolved gas is carbon dioxide.
e) Ethanoic acid Es used in
a) for preservation of pickles
b) for preparation of dyes, drugs
C) for solvent in industry
d) for curing meat, fish.
Multiple choice questions

Question 1.
Which of the following solution of acetic acid in water can be used as preservative? [ ]
(a) 5-10%
(b) 10-15%
(c) 15-20%
(d) 100%

Answer:
(a) 5-10%

Question 2.
The suffix used for naming an aldehyde is [ ]
(a) -0l
(b) -al
(c) -one
(d) -ene

Answer:
(b) -al

Question 3.
Acetic acid, when dissolved in water, it dissociates into ions reversibly because it is a:[ ]
(a) Weak acid
(b) strong acid
(c) weak base
(d) strong base

Answer:
(a) Weak acid

Question 4.
Which one of the following hydrocarbons can show isomerism? [ ]
(a) C2H4
(b) C2H6
(c) C3H8
(d) C4H10

Answer:
(d) C4H10

Question 5.
Combustion of hydrocarbon is generally accompanied by the evolution of [ ]
(a) Heat
(b) Light
(c) both heat and light
(d) Electric current.

Answer:
(c) both heat and light

Question 6.
2m1 of ethanoic acid was taken in each of the three test tubes A, B and C’ and 2m1. 4ml and 8 ml of water was added to them, respectively. A clear solution is obtained in: [ ]
(a) Test tube A only
(b) Test tubes A & B only.
(c) Test tubes B and C only
(d) All the test tubes.

Answer:
(d) All the test tubes.

Question 7.
If 2 ml of acetic acid was added slowly in drops to 5m1 of water then we will notice [ ]
(a) The acid forms a separate layer on the top of water.
(b) Water forms a separate layer on the top of the acid.
(c) Formation of a clear and homogenous solution.
(d) Formation of a pink and clear solution.

Answer:
(c) Formation of a clear and homogenous solution.

Question 8.
A few drops of ethanoic acid were added to solid sodium carbonate. The possible results of the reactions are: [ ]
(a) A hissing sound was evolved
(b) Brown fumes evolved.
(c) Brisk effervescence occurred.
(d) A pungent-smelling gas evolved.

Answer:
(c) Brisk effervescence occurred.

Question 9.
When acetic acid reacts with ethyl alcohol, we add cone. H2SO4, which acts as and the process is called [ ]
(a) Oxidizing agent, saponification
(b) Dehydrating agent, estenfication
(c) Reducing agent, Esterification
(d) Acid & esterification

Answer:
(b) Dehydrating agent, estenfication

Suggested Experiments

Question 1.
Suggest a test to find the hardness of water and explain the procedure.

Answer:
Hardness of water can be tested with the help of a good quality soap.
Procedure
Take 50ml of water from different sources i.e., tap water, well water, lake water, pond water, river water, etc., in different test tubes and lable them as A, B, C, D etc.
Add 1gm of good-quality soap to each test tube.
Close each test tube with rubber corks.
Shake test tube A for 15 seconds and keep it undisturbed for 30 seconds. Measure the height of the foam formed. Note the height of foam in your notebook.
Repeat the process for each test tube and record your observation in your notebook.
The water which gives less foam is considered as hard water.

Question 2.
Suggest a chemical test to distinguish between ethanol and ethanoic acid and explain the procedure.

Answer:
Take ethanol and ethanoic acid in two different test tubes.
Add nearly 1gm of sodium bicarbonate (NaHCO3) to each test tube.
Lots and lots of bubbles and foam will be observed from the test tube containing ethanoic acid. This is due to release of CO2.
NaHCO3 + CH3COOH → CH3COONa + H2O + CO2
Ethanol will not react with sodium bicarbonate and thus we won’t observe any change in the test tube containing ethanol. Thus we can seperate ethanol from ethanoic acid.

Question 3.
An organic compound ‘X’ with a molecular formula C2H6O undergoes oxidation with alkaline KMnO4 and forms the compound ‘Y’, that has molecular formula C2H4O2.
(a) Identify "X"and "Y".

Answer:
X : C2H6O is Ethanol
Y: C2H4O2 is Ethanoic acid
Ethyl alcohol undergoes oxidation to form the product Acetaldehyde and finally Acetic acid.

This CH3COOH is used as preservative for pickles.
(b) Write your observation regarding the product when compound ‘X’is made to react with compound "Y" which ¡s used as a preservative for pickles.

Answer:
When x (ethanol) is reacted with y (ethanoic acid) in the presence of concentrated H2S04 to form fruity odour substance called ester (ethyl acetate)

Here CH3COOH is used as preservative for pickles.

Suggested Projects

Question 1.
Prepare models of methane, ethane, ethene and ethyne molecules using clay balls and match sticks.

Answer:

in these models Black Ball is Carbon atom White Ball is Hydrogen atom.

Question 2.
Collect information about artificial ripening of fruits by ethylene.

Answer:
Chemistry of ripening:
During ripening, the starch in the fruit breaks down to form sugar. The fruit skin changes its colour.
The ripening of fruit depends on the season. The plant can detect the changes in season. They produce ethylene (C2H4) which spreads across the plant.
When ethylene reaches the fruits, it sends a signal to ail the cells in the fruit to make enzymes which break starch into sugar.
The cells in the skin start making pigments, which give the fruit its colour.

Artificial ripening:
Raw fruits are kept in hay-lined wooden boxes called crates. These crates are stacked on shelves and a wood fire s lit below them. The smoke contains ethylene and acetylene gases, which induce ripening.
Fruits are placed in a room into which ethylene gas or acetylene gas is introduced.
In another method calcium carbide (CaC2) is applied over fruits. It reacts with moisture to form acetylene, which induces ripening.

TS 10th Class Physical Science Carbon and its Compounds Intext Questions

Page 253

Question 1.
Can carbon get helium configuration by losing four electrons from the outer shell?

Answer:
No. if carbon loses four electrons from the outer shell, it has to form C+4 ions. This requires huge amount of energy which is not available normally.

Page 254

Question 2.
How do carbon atoms form bonds in so many ways

Answer:
Electronic configuration of carbon (ground state) is 1S2 2S2 2P2 (or) 1S2 2S2 2Px1 2Py1 2Pz1

Electronic configuration of carbon (excited state):

In excited state of carbon atom one ‘2s’ electron Is promoted to ‘2Pz’ orbital. Each carbon In excited state has four unpaired electrons and forms four covalent bonds as shown below.


Question 3.
Explain the four unpaired electrons in carbon atom through excited state

Answer:
Electronic configuration of carbon (ground state)

Electronic configuration of carbon (excited state)

So, in 2s,2p orbitals there are four unpaired electrons In each of 2s, 2px, 2py, and 2pz orbitals.

Page 255

Question 4.
Where this energy to excited electron comes from?

Answer:
The energy required for excitation is taken up from bond energies, which are liberated energies and four bonds are formed between carbon atoms and other atoms.

Question 5.
In methane (CH4) molecule, all four carbon-hydrogen bonds are identical and bond angle
HCH is 109° 28’. How can we explain this?

Answer:
In methane (CH4), in excited state, carbon atom has three unpaired electrons in p-orbitals, and one electron in s-orbital. So all four C-4 bonds are identical.

Question 6.
How these energetically unequal valence electrons form four equivalent covalent bonds in methane molecules?

Answer:
The energy difference between the 2s and 2p orbitals is very small.
When carbon atom is ready to form bonds it gets a small amount of energy from bond energies and gets excited and is promoted from the ‘2s’ to the empty 2pz to give four unpaired electrons.
These four unpaired electrons form four equivalent covalent bonds in methane.

Page 259

Question 7.
What are bond angles of HCH in CH4, C2H4 and CH3 molecules?

Answer:
The bond angles:
In CH4 is 109°28′
In C2 H4 is 120°
In C2H2 Is l80°

Page 261

Question 8.
How do you understand the marking (writings) of a pencil on a paper?

Answer:
When we write with a pencil, the interlayer attractions break down and leave graphite layers on the paper. These pencil marks are easy to remove from paper with an eraser because the layers do not bind strongly to the paper.

Page 264

Question 9.
AllottIng completely one special branch in chemistry to compounds of only one element. Is It justified when there are so many elements and their compounds but not with any special branches?

Answer:
We know that all molecules that make life possible, namely, carbohydrates, proteins, nucleic acids, lipids, harmones and vitamins contain carbon.
The chemical reactions that take place in living systems are of carbon corn pounds.
Food that we eat, various medicines we use cotton and silk fibres, synthetic fibres, plastics, synthetic rubber are also compounds of carbon.
So, Carbon Is a unique element with the largest number of compounds.
So allotting completely one special branch in chemistry to carbon is justified.

Page 265

Question 10.
What are hydrocarbons?

Answer:
The compounds containing only carbon and hydrogen in their molecules are called ‘Hydrocarbons’.

Question 11.
Do all the organic compounds have equal number of ‘C’ and ‘H’ atoms?

Answer:
No. Different organic compounds have different number of ‘C’ and ‘H’ atoms.

Page 266

Question 12.
Can carbon form bonds with the atoms of other elements?

Answer:
It Is observed that carbon atoms form compounds not only with hydrogen atoms but also with atoms of other elements like oxygen, sulphur, nitrogen, phosphorus, halogens etc. These atoms are called heteroatoms and the compounds are formed with particular functional groups.

Page 269

Question 13.
How about their structures? Are they same?

Answer:
The structures are not the same. They are different.

Question 14.
How many carbon and hydrogen atoms are there In (a) and (b) structures?

Answer:
In structure (a) there are 4 carbon atoms and 10 hydrogen atoms.
In structure (b) also there are 4 carbon atoms and 10 hydrogen atoms.

Question 15.
Write the condensed molecular formulae for (a) and (b). Do they have same molecular formulae?

Answer:
The condensed molecular formula for (a) is C4H10.
The condensed molecular formula for (b) is C4H10.
Both (a) and (b) have the same condensed molecular formula. (Isomers)

Page 280

Question 16.
Why do sometimes cooking vessels get blackened on a gas or kerosene stove?

Answer:
Because of Inlets of air getting closed, the fuel gases do not completely undergo combustion. Hence, it forms a sooty carbon form (black in colour) which gets coated over the vessels.

Page 283

Question 17.
Do you know how the police detect whether suspected drivers have consumed alcohol or not?

Answer:
The police officer asks the suspected driver to blow air into a plastic bag through a mouthpiece of the detecting instrument which contains orange-coloured crystals of potassium dichromate (K2Cr2O7).
As K2Cr2O7 is a good oxidising agent ethanol which is in the driver’s breath changes to ethanoic add. The orange colour changes to green and the police can detect that the driver has consumed alcohol.

Page 284

Question 18.
What are esters?

Answer:
The reaction between carboxylic acid and an alcohol ‘n the presence of conc H2SO4 produces a sweet-smelling substance called ester.
An ester contains the functional group: - C - COOR

Question 19.
What do you notice?

Answer:
We notice that the resulting mixture is a sweet-smelling substance and is known as ethyl acetate, an ester.

Page 285

Question 20.
Do you know what ‘soap’ is?

Answer:
Soap is a sodium or potassium salt of a higher fatty acid like palmitic acid (C15H31COOH), stearic acid (C17H35COOH) Oleic acid (C17H33COOH) etc.
The formula of soap is RCOONa (or) RCOOK
R = C15H31; C17,H35 etc.

Page 286

Question 21.
What isatrue solution?

Answer:
A true solution is that in which the solute particles dispersed In the solvent are less than mm (10-9m) in diameter.

Question 22.
Can you see the oil and water layers separately in both the test tubes.

Answer:
(a) Immediately after: You stop shaking them?

Answer:
No,
(b) Leave the test tubes undisturbed for sometime and observe. Does the oil layer separate out?

Answer:
Yes. After allowing test tubes to settle for some time. the oil layer floats on water layer.
(c) in which test tube does this happen first? Give your observations?

Answer:
The oil layer and water layer separate first in test tube B, with soap water.

Page 287

Question 23.
What is the action of soap particles on the greasy cloth?

Answer:
The soap particles make oil and dirt present on the cloth come out into water, thereby making the cloth clean.

Think And Discuss
Question 1.
Why we are advised not to use animal fats for cooking?

Answer:
Fats are generally solids at room temperature. Animal fats have saturated carbon chains. Hence they require large quantities of heat to break those chains. In this process a lot of fuel is consumed. So, we are advised not to use animal fats for cooking.

Question 2.
Which oil is recommended for cooking? Why?

Answer:
Generally, vegetable oils having long unsaturated carbon chains are recommended for cooking.
Reasons:
They do not require large quantities of heat to break the carbon chains.
So we can save cooking fuel.
Secondly, it does not take long time to cook food which prevents over cooking which is harmful to health.

TS 10th Class Physical Science Carbon and its Compounds Activities
Activity 1

Question 1.
Observe the names of the following compounds. Give reasons in the space provided. (ASS) (4 Marks)

Answer:
COOH > (CH3CO)2O> - COOR > -COX> -CONH2 > -CN > - CHO > C=O > R-OH> -NH
Acid anhydride ester acid halide amide nitrite aldehyde ketones alcohols amines
Divide the given names as per the notations given and identify the parts In the name through the numbers given from (1) to (11) and write them in your notebook.




Activity 2

Question 1.
Write an activity to show esterification.

Answer:
Take imI of ethanol and imI of glacial acetic acid along with a few drops of concentrated sulphuric acid in a test tube.
Warm it In a water bath or a beaker containing water for at least 5 minutes as shown In fig.
Pour the warm contents into a beaker containing 20-50 ml of water and observe the odour of the resulting mixture.
Observation: The resulting mixture Is a sweet odoured substance. This substance is ester. This reaction is esterification.


Activity 3

Question 1.
How do you test the cleansing action of soap?

Answer:
1. Take about 10 ml of water in two test tubes.
2. Add a drop of cooking oil to both the test tubes and label them as A and B.
3. Add a few drops of soap solution to test tube B.
4. Now shake both the test tubes vigorously for the same period of time.
5. We cannot observe that the oil and water layers separately in both the test tubes immediately after shaking Is stopped.

6. Leave the test tubes undisturbed for some time and observe.
7. We observe the separation of oil layer in test tube B first because it contains the soap solution.
8. This gives an idea of cleansing action of soap.

Important Question

TS 10th Class Physical Science Important Questions Chapter 12 Carbon and its Compounds
1 Mark Questions

Question 1.
What is allotropy

Answer:
An element exists in two or more different forms due to the difference in their atomic arrangement is called Allotrophy and the different forms are called allotropes.

Question 2.
Explain briefly about the structure of ‘Diamond’.

Answer:
In a diamond, each ‘c’ is surrounded by four other ‘c’ atoms.
These are placed at the four corners of a regular tetrahedron.
This results in a 3-dimensional network of carbon atoms.

Question 3.
Explain briefly about the structure of "Graphite".

Answer:
In graphite, each ‘c’ is surrounded by three other ‘c atoms.
The ‘c’ atoms are arranged in layers.
Each layer consists of a 2-dimensional hexagonal network.

Question 4.
"Diamond is an extremely bad conductor of electricity." Why?

Answer:
In a diamond, each carbon atom is covalently bonded with four other carbon atoms.
So, the four outermost electrons of a carbon atom are engaged or trapped in the covalent bonds, having no free electrons makes it a bad conductor of electricity.

Question 5.
What is an alkyl group’

Answer:
If one hydrogen is removed from an alkane, it is called alkyl group.
Eg : CH4 → methane
CH3 → methyl group

Question 6.
What is the bond length in diamond?

Answer:
The C - C bond length In diamond is 1.54 Å.

Question 7.
What is polymerization?

Answer:
The reaction In which a large number of identical and simple molecules Join together to form a large molecule is called "Polymerization.


Question 8.
Name some functional groups.

Answer:

Question 9.
What is the bond angle in diamond?

Answer:
The bond angle in diamond is 109° 28’.

Question 10.
What is the C-C bond length in graphite?

Answer:
The C-C bond length in graphite is 1.42 A.

Question 11.
What is the bond angle in graphite?

Answer:
The bond angle in graphite is 120°.

Question 12.
What is hydrocarbon?

Answer:
Compounds containing only carbon and hydrogen are called hydrocarbons.
Eg: Alkanes (Saturated hydrocarbons)
Alkenes and Alkynes (unsaturated hydrocarbons)

Question 13.
What are saturated hydrocarbons? (or) What are alkanes?

Answer:
The valency of the carbon is four 4, of all the valencies of carbon are satisfied, the resultant hydrocarbons are refer to as saturated hydrocarbons or Alkanes. They general formula is CnH2n+2.

Question 14.
What are unsaturated hydrocarbons?

Answer:
The hydrocarbons containing one or more double bonds or triple bonds between two carbon atoms are called "Unsaturated hydrocarbons.
Eg: C2H6 and C3H6 etc.

Question 15.
What are alkanes? Write the general formula of alkenes. Give an example for alkenes.

Answer:
Alkenes: Hydrocarbons containing at least one double bond between carbon atoms are called Alkenes (>C=C<)
General formula: CnH2n
Examples : Ethene (C2H4, Propene (C3H6)

Question 16.
What are Alkynes?

Answer:
Alkynes are unsaturated hydrocarbons having at least (CC) triple bonds In these structures. Their general formula is CnH2n-2.
Eg: Acetylene (HC ≅ CH)

Question 17.
What is Homologous series?

Answer:
A series of compounds in which the same functional group substitutes for hydrogen in a carbon chain is called a homologous series.

Question 18.
Give the names of the functional group.

Answer:
(i) - CHO- Aldehyde

(iii) - OH - Alcohol
(iv) - COOH - Acid (carboxylic acid)

Question 19.
What do you mean by a functional group?

Answer:
The characteristic properties of an organic compound depend mainly on an atom or group of atoms In its molecule known as the ‘functional group’, Functional group is responsible for the behavior of the organic compounds.

Question 20.
What is the difference between two successive homologs?

Answer:
Successive compounds in a homologous series possesses a difference of (CH3) unit and are called homologs.

Question 21.
Write the structure of 3 - bromo - 2 - chloro - 5 0x0 hexanoic acid.

Answer:

Question 22.
Why graphite is a good conductor of electricity?

Answer:
Graphite Is a good conductor of electricity because of the delocalized π electron system.

Question 23.
What are the uses of fullerenes?

Answer:
Fullerenes are under study for potential medicinal use such as specific antibiotics to target resistant bacteria and even target certain cancer cells such as melanoma.

Question 24.
What are oxidizing agents?

Answer:
Oxidizing agents or oxidants are substances that oxidize other substances.

Question 25.
Why do we call alkanes as paraffins?

Answer:
Alkanes are saturated hydrocarbons with least reactivity. Therefore they are called paraffins (Parum = little: affine affinity).

Question 26.
Write two uses of Ethanol In day-to-day life.

Answer:
Ethanol is used in
Preparation of Alcoholic drinks
Preparing tincture iodine
Preparing cough syrup and tonics

Question 27.
What is the use of ethanol ¡n motors?

Answer:
If we add 10% ethanol to gasoline it will act as very good motor fuel.

Question 28.
What is a colloidal solution?

Answer:
If the diameter of dispersed phase Is greater than 1 nm but less than 1000 nm in a dispersed medium such a solution Is called colloidal solution.

Question 29.
Other than carbon which elements show catenation?

Answer:
Sulphur, phosphorus, and silicon.

Question 30.
What are the other names given to open-chain hydrocarbons?

Answer:
Open-chain hydrocarbons are also called as aliphatic hydrocarbons or acyclic hydrocarbons.

Question 31.
Expand IUPAC.

Answer:
International Union of Pure and Applied Chemistry.

Question 32.
Name the following compound.

Answer:
2, 3 - dimethyl - cyclo hexane- 1 - ol

Question 33.
How do you appreciate the role of diamonds In space probes?

Answer:
Since it has the ability to filter out harmful radiation, it is used in making protective windows for space probes.

Question 34.
How do you appreciate the role of diamonds in surgery?

Answer:
A sharp-edged diamond is used as a tool to remove cataracts In eye surgery.

Question 35.
How do you appreciate the role of oxygen in combustion process?

Answer:
When the oxygen supply is insufficient then the fuels burn incompletely Hoducing mainly a yellow flame.
When the oxygen supply is sufficient then the fuels burn completely producing
a blue flame.

Question 36.
How do you appreciate the role of Ethanol as a fuel?

Answer:
A material which Is burnt to obtain heat is called a fuel. Since ethanol burns with a clear flame giving a lot of heat, it is used as a fuel.
Some countries add ethanol to petrol to be used as a fuel in cars. Thus ethanol is used as an additive in petrol.
Ethanol alone can also be used as a fuel for cars.

Question 37.
How do you appreciate the role of active acid as a preservative?

Answer:
Dilute acetic acid Is used as a food preservative In the preparation o! pickles and sauces.
As vinegar, it is also used as an appetizer for dressing food dishes.

Question 38.
How do you detect leakage in the cylinder?

Answer:
To detect any leakage of gas from the cylinder a strong-smelling substance like ethyl mercaptan (C2H5SH) Is added to the gas.
Then the leakage can be easily detected by the foul smell of the ethyl mercaptan.

Question 39.
What are nanotubes?

Answer:
Nanotubes are allotropic form of carbon.

Question 40.
Write the molecular formula of the fourth member of the homologous series of alcohols.

Answer:
CH3- CH2- CH2 - CH2- OH

Question 41.
What is a catalyst?

Answer:
The substance which does not take part In chemical reaction but changes the rate of reaction is called a catalyst.

Question 42.
Why oils are in liquids at room temperature?

Answer:
Oils are unsaturaoð compounds so they are In liquid state.

Question 43.
Why fats are solids at room temperature?

Answer:
They are saturated compounds so they are in solid state.

Question 44.
Do you know the police detect whether suspected drivers have consumed alcohol or not? Explain.

Answer:
Orange Cr2O72- changes bluish-green Cr3+ during the process Of the oxidation of alcohol. The Ieiqth of the tube that turned into green is the measure of the quantity of alcohol that had been drunk.

Question 45.
What is pica?

Answer:
The negative value of logarithm of dissociation constant of an acid.

Question 46.
Name the gas evolved when acetic acid is react with sodium hydrogen carbonate.

Answer:
The gas liberated is carbon dioxide.

Question 47.
Name the organic add present In vinegar - write Its chemical formula.

Answer:
The acid present In vinegar is acetic acid. its formula is CH3COOH.

Question 48.
What change will you observe If you test soap with litmus papers?

Answer:
Red litmus turns into blue.

Question 49.
Write the valency of carbon In CH3- CH3, CH2 = CH2, and HC ≅ CH?

Answer:
The valency of carbon in CH3- CH3, is 4.
The valency of Carbon in CH2 = CH2 is 3.
The valency of carbon In HC ≅ C - H is 2.

Question 50.
Out of butter and ground nut oil which Is unsaturated In nature?

Answer:
Ground nut oil is unsaturated In nature.

Question 51.
What are hydrophobic and hydrophilic parts in soap?

Answer:

Question 52.
Name the carboxylic acid used as preservation.

Answer:
Acetic acid used as preservative.

Question 53.
Write two uses of nanotubes.

Answer:
Nanotubes are used to connect the components of integrated circuits instead of copper.
Biomolecules are inserted into nanotubes to inject them into a single cell.

2 Marks Questions

Question 1.
Identify the functional groups In the following compound arid write IUPAC names.


Question 2.
What are alkenes?

Answer:
Alkenes are unsaturated hydrocarbons having at least one(C=C) double bond in these structures. Alkenes are also called olefins. Their general formula is Cn- H2n Eg: Ethylene (C2H4) and propene (C3-H6) etc.

Question 3.
Which of the following compounds are unsaturated? Justify your answer.
(a) CH3-CH2-CH3
(b) CH3 - CH = CH2

(d) HC ≅ C - CH = CH2

Answer:
a and f are saturated hydrocarbons because they have only single bonds. Remaining are unsaturated hydrocarbons as they have double or triple bonds.

Question 4.
What are hydrophilic and hydrophobic parts In soaps? (AS1)

Answer:
The polar end in soap with carboxy C-Ois called hydrophilic end. The non-polar end ¡n soap with hydrocarbon chain is called hydrophobic end.


Question 5.
What is the order to be followed while naming carbon compounds?

Answer:
The following order is to be followed while naming carbon compounds. Numbers-Numerical Prefixes-Secondary Prefix-Primary Prefix-Word Root-


Question 6.
Explain addition reactions.

Answer:
Unsaturated organic compounds that contain multiple bonds like alkenes and alkynes became saturated by addition of a reagent are called addition reactions. During the reactions addition of the reagent takes place at the double-bonded or triple-bonded carbon atoms.


Question 7.
What type of reaction takes place between ethane and chlorine?

Answer:
Substitution reaction takes place between ethane and chlorine In the presence of sunlight.
CH4 + Cl2 → CH3Cl + HCl
CH3Cl+ Cl2 → CH2Cl2 + HCl
CH2Cl2 +Cl2 → CHCl3 + HCl
CHCl3 + Cl2 → CCl4 + HCl

Question 8.
An organic compound X with a molecular formula C2H6O undergoes oxidation with in presence of alkaline KMnO4 to form a compound y. X on heating in presence of con. H2SO4 at 443 k gives Z. Which on reaction with Br2 and decolorizes, It. Identity X, Y, and Z write the reactions involved.

Answer:

Question 9.
How synthetic detergents are harmful for environment?

Answer:
Some synthetic detergents resist biodegradation, i.e., they are not decomposed by microorganisms such as bacteria.
Hence, they cause water pollution In lakes and rivers.
They tend to persist for a long time, making the water unfit for aquatic life.

Question 10.
Write the reactions of Ethanol with sodium and conc. H2SO4

Answer:
Ethanol reacts with sodium metal to liberate hydrogen and forms sodium ethanoxide.
2C2H5OH + 2Na → 2C2H5ONa + H2
Ethanol reacts with conc. H2SO4 at about 170°C to give ettiene.
CH3CH2OH CH2 = CH2 + H2O

Question 11.
Write the reactions of Ettianoic acid with metals, metal hydroxide, metal carbonates, and metal hydrogen carbonates.

Answer:
1. ReactIon of ethanoic acid with metal: Ethanoic add reacts with active metals like Na to liberate hydrogen.
2CH3COOH + 2Na → 2CH3COONa + H2
2. Reaction of ethanoic acid with metal hydroxide: Ettianoic acid reacts with NaOH to form salt and water.
CH3COOH + NaOH → CH3COONa + H2O
3. Reaction of ethanoic acid with metal carbonates and metal hydrogen carbonates: Ethanoic acid reacts with sodium carbonate and sodium hydrogen carbonate and liberates CO2
2CH3COOH + Na2CO3 → 2CH3COONa + H2O + CO2
CH3COOH + NaHCO3 → CH3COONa + H3O + CO2

4 Marks Questions

Question 1.
Draw the structures of Isomers of butane.

Answer:
Isomers of butane are n-butane, isobutane and cyclobutane Structures:


Question 2.
explain the Isomerism and Catenation properties of Carbon.

Answer:
Catenation properties of carbon :
(i) Carbon has ability to form longest chains with its own atoms. This special property of carbon is called catenation.
(ii) Due to catenation property of carbon it can form largest chain containing millions of carbon atoms, branches and acidic compounds.

Isomerism of carbon: The phenomenon of possessing some molecular formula but different properties by the compounds is known as isomerism.

The molecular formula of above two molecules is C4H10 but they have different structures.
These two are isomers
By there two special properties of carbon it can make number of compounds.

Question 3.
Draw the structures of the following.
a) Ethanoic acid
b) Propanol
c) Propene
d) Chloro propene

Answer:
Structures



Question 4.
Draw structure of Ethane and electron dot structure of Chlorine.

Answer:
Ethane:


Question 5.
Draw the structures of the following compounds.
(a) 2 - Bromo pentane
(b) 2 - methyl propane
(c) butanol
(d) 1-hexine

Answer:

(c) butanol : CH3 - CH2 - CH - CHO
(d) 1 - hexine : CH3 - CH2 - CH2 - CH2 - C ≅ C - H

Question 6.
Draw the electron dot structures of Ethanoic acid and Ethyne (Acetylene)

Answer:
Ethanoic acid (Acetic acid):



Question 7.
Write the molecular formula of the first tour compounds of the homologous series of aldehydes.

Answer:
Homologous series of aldehydes are Formaldehyde, Acetaldehyde. Propionaldehycie arid Butanaidehyde.


Question 8.
How many Isomers can be drawn for pentane with molecular formula C5H12? What are they? Draw their structures and mention their common names.

Answer:
Isomers of pentane are three. These are
Pentane
Iso pentane
Neo pentane.
Structures:



Question 9.
Explain sp3 hybridization In methane.

Answer:
The excited carbon atom allows use S-orbital. (2s) and three p-orbitals (2px,
2py, 2pz) to intermix and reshuffle Into four identical orbitals known sp3 orbitals. Thus carbon atom undergo sp3 hybridization. The four electrons enter into the new four identical orbitals known as sp3 orbitals, one each as per Hund’s rule.

1. Since carbon has four unpaired electrons, t is capable of forming bonds with four other atoms.
2. When carbon reacts with hydrogen, four hydrogen atoms allow their ‘s’ orbitals containing one electron each to overlap with four sp3 orbitals of carbon-atom which are oriented at an angle of 109°. 28’.
3. Four orbitals of an atom in the outer shell orient along the four comers of a tetrahedron to have minimum repulsion between their electrons. The nucleus of the atom is at the centre of the tetrahedron.
4. This leads to form four sp3 - s - sigma bonds between carbon atom and four hydrogen atoms. All these bonds are of equal energy.


Question 10.
Explain sp2 Hybridisation with an example.

Answer:
Consider ethene molecule
In the formation of CH2 = CH2 each carbon atom in its excited State undergoes sp2 hybridization by Intermixing one s-orbital (2s) and two p-orbitals (say 2px and 2py) and reshuffling to form three sp2 orbitals.
Now each carbon atom Is left with one ‘p’ orbital (say 2Pz) subsidized.
The three sp2 orbitals having one electron each get separated around the nucleus of carbon atoms at an angle of 120°.
When carbon Is ready to form bonds one sp2 orbital of one carbon atom overlaps the sp2 orbital of the other carbon atom to form sp2 - sp1 sigma (s) bond.
The remaining two sp2 orbitals of each carbon atom get overlapped by ‘s’ orbitals of two hydrogen atoms containing unpaired electrons.
The unhybridized pz orbitals on the two carbon atoms overlap laterally as shown in figure to form π bond.
Hence, there exists a sigma (σ) bond and a pi (π) bond between two carbon atoms In ethene molecule. Hence, the structure of molecule ethane (C2H4)


Question 11.
Explain sp hybridisation.

Answer:
Each carbon is only Joining to two other atoms rather than tour or three.
Here the carbon atoms hybridise their outer orbitals before forming bonds, this time they only hybridise two of the orbitals.
They use the ‘s’ orbital (2s) and one of the sp orbitals, by leave the other 2p orbitals unchanged.
The new hybrid orbitals formed are called sp-hybrid orbitals because they are made by an s-orbital and a p-orbital reorganizing themselves.

Question 12.
Define substitution reaction and give an example

Answer:
A reaction in which one atom or a group of atoms in a given compound is replaced by other atom or group of atoms is called a substitution reaction. Alkanes undergo substitution reactions. Exampler Methane (CH4) reacts with chlorine in the presence of sunlight.


Question 13.
Give next Homologs of the following compounds and also give structure formula and name. (1) HCHO (2) CH3OH

Answer:

HornologFormula Name
CH3CHOC2H4O Ethanal
CH3CH2CHO C3H6OPropanal
CH3CH2CH2CHO C4H8OButanal
CH3CH2CH2CH2CHO C5H10OPentanal
Question 14.
Write the IUPAC names of the following compounds. (AS1)
i) CH3 - CH0 - CH2 - CH2 - CH2 - CH2 - CH2 - CH2CH2OH
ii) CH3 - CH2 - CH = CH2 - C ≅ CH
iii) CH3 - CH2- CH2- CH2 - CHO
iv) CH3 - CH2 - CH2 - CH2 - COOH

Answer:
1) nananol
2) 4 - ene 1 hexyne
3) pentanol
4) pentanoic acid

Question 15.
Complete the following reactions.

Answer:

Question 16.
Draw the electronic dot structure of ethane molecule.

Answer:

Question 17.
Draw the structure of the following compounds.

Answer:

Question 18.
Draw various structures of (a) C5H12 (b) C6H14.

Answer:


Question 19.
Draw the structuie of butanoic acid C3H7COOH.

Answer:
Formula of butanoic acid is C4H8O2.

Structure:

Question 20.
Draw the diagram showing sp2 hybridization In Ethene.

Answer:

Question 21.
Draw the diagram showing sp hybridisation in Ethyne.

Answer:

Question 22.
List out the materials required to conduct the experiment to understand the esterification reaction. Explain the procedure of the experiment. How can you identify that an ester is formed In this reaction?

Answer:
Materials required:
Test tube, beaker, water, burner wire gauze, tripod stand, 1ml. of ethanol, 1ml of glacial acetic acid, and few drops of conc. H2SO4


1) Take 1 ml of ethanol and imI of glacial acetic acid along with a few drops of concentrated sulphuric acid in a test tube.
2) Warm It In a water bath or a beaker containing water for at least 5 minutes as shown in fig.
3) Pour the warm contents into a beaker containing 20-50 ml of water and observe the odour of the resulting mixture.
Observation: The resulting mixture is a sweet odoured substance. This substance Is ester. This reaction is esterification, Ester is a sweet-smelling compound. We can identify an ester by its sweet smelling.
Do You Know?
1. Linus Pauling - The world’s one of the greatest scientist and a great humanist. He was acknowledged as the most influential chemist. He is the only person ever to receive two unshared Nobel Prizes - for Chemistry(1954) and for Peace (1962). (Page 255)

2. The buckminsterfullerene, or usually just fullerene for short, was discovered in 1985 by a team of scientists, Robert F. Curl, Harold W. Kroto, and Richard E. Smalley from Rice University and the University of Sussex, three of whom were awarded the 1996 Nobel Prize in Chemistry. They are named so for the resemblance of their structure to the geodesic structures devised by the scientist and architect Richard Buckminster "Bucky" Fuller. (Page 261) 3. Graphene: The new wonder material: As its name indicates, graphene is extracted from graphite, the material used in pencils. Like graphite, graphene is entirely composed of carbon atoms. For a thickness of 1mm, graphite contains some 3 million layers of graphene. The carbons are perfectly distributed in a hexagonal honeycomb formation only in 0.3 nanometers thickness. Graphene conducts electricity better than copper. It is 200 times stronger than steel but six times lighter. It is almost perfectly transparent to light. (Page 263)
4. Wohier Friedrich (1800 - 1882): German Chemist who was a student of Berzelius In attempting to prepare ammonium cyanate from silver cyanide and ammonium Chloride. he accidentally synthesized urea in 1828. This was the lust organic synthesis and shattered the vitalism theory.
Wohier pursued the matter further and discoiered that urea and ammonium cyanate had the same chemical fo.rnula, but very different chemical properties. This was an early discovery of Isomerism since urea has the formula CO(NH2)2 and ammonium cyanate has the formula NH4CNO. (Page 264) 5. We may compare amines to as we have done RON and R - 0 - R’ to H2O. If one Hydrogen Atom is replaced from NH3 by an alkyl group we get primary amines. If two hydrogen atoms of NH3 are replaced by two alkyl groups (same or different) we get secondary amines and if all the three hydrogen atoms are replaced by the same or different alkyl groups we get tertiary amines. (Page 269) 6. The police officer asks the suspect to blow air Into a plastic bag through a mouthpiece of the detecting instrument which contains crystals of potassium di-chromate (K2Cr2O7). As K2Cr2O7 is a good oxidizing agent, it oxidizes any ethanol in the driver’s breath to ethanoic acid, Orange Cr2O72- changes to bluish-green Cr3+ during the process of the oxidation of alcohol The length of the tube that turned into green is the measure of the quantity of alcohol that had been drunk. Nowadays police are using even an electronic Instrument containing small fuel cell that measures the electrical signal produced when ethanol is in the breath is oxidized. The police even use the IR Spectra to detect the bonds C - OH and C - H of CH3- CH2OH. (Page 283)

Question Papers / Notes Download


Videos


Join
Intermediate
-